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Chemical

Glyoxal

CAS 107-22-2 · EC 203-474-9 · C2H2O2

Also known as ethanedial, oxaldehyde

Sold as a roughly 40% aqueous solution. Used as a safer alternative to formaldehyde for hardening gelatin sizing, but it is still a suspected mutagen, a skin sensitiser and harmful if inhaled.

Signal word
Warning
CAS
107-22-2
EC number
203-474-9
UK/EU status
No UK or EU restrictions recorded

Handle chemistry safely

Wear gloves and eye protection, work with good ventilation, and read the supplier’s safety data sheet before use. Hazard information here is a summary, not a replacement for it. Dispose of all photographic chemistry correctly, in line with local laws and your local authority’s guidance. Never mix waste solutions, and check the supplier’s safety data sheet before disposing of anything.

Hazards

Official EU classification (CLP Annex VI).

Harmonised classes (for the solution, 'glyoxal ...%'): Muta. 2 (H341); Acute Tox. 4 (Inhalation)* (H332); Skin Irrit. 2 (H315); Eye Irrit. 2 (H319); Skin Sens. 1 (H317). Asterisked codes in Annex VI denote minimum classification/route not specified.

Signal word: Warning

Serious health hazard · Harmful or irritant

CodeHazard statement
H341Suspected of causing genetic defects.
H332Harmful if inhaled.
H315Causes skin irritation.
H319Causes serious eye irritation.
H317May cause an allergic skin reaction.

Photographic uses

  • gelatin size hardener for gum bichromate and gum over platinum or cyanotype paper (Harmon)